Stable ruthenium nitrosyl porphyrins with axial O-bonded ligands; preparation and redox behavior.

نویسندگان

  • Dennis Awasabisah
  • Nan Xu
  • Krishna P Sharmah Gautam
  • Douglas R Powell
  • Michael J Shaw
  • George B Richter-Addo
چکیده

The six-coordinate compounds, (T(p-OMe)PP)Ru(NO)(OC6HF4) and (T(p-OMe)PP)Ru(NO)(OC(=O)CF3) have been prepared and characterized by IR and NMR spectroscopy, electrochemistry and IR spectroelectrochemistry, and by X-ray crystallography. These compounds undergo macrocycle-centered oxidations, and loss of axial ligands upon reduction.

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عنوان ژورنال:
  • Dalton transactions

دوره 42 24  شماره 

صفحات  -

تاریخ انتشار 2013